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Chemical Identification
Common Name
Phenothrin
中文通用名
苯醚菊酯
IUPAC
3-phenoxybenzyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
or
3-phenoxybenzyl (1RS)-cis-trans-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
or
3-phenoxybenzyl (±)-cis-trans-chrysanthemate
CAS
(3-phenoxyphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
CAS No.
26002-80-2
Molecular Formula
C23H26O3
Molecular Structure
Category
Activity
Insecticide
Pest Spectrum
targets ants, aphids, bed bugs, bees, beetles, billbugs, box elders, borers, cockroaches, cadelles, caterpillars, centipedes, crickets, daubers, earwigs, fleas, flies, gnats, hornets, crawling insects, flying insects, grain insects, lace bugs, leafhoppers, leaf miners, lice, moths, mites, mealy bugs, midges, millipedes, mosquitoes, rust, scab, scales, scorpions, silverfish, spiders, sow bugs, thrips, ticks, wasps, waterbugs, weevils, worms, and yellow jackets
Premix
PRALLETHRIN+CYPHENOTHRIN
CYPHENOTHRIN+TETRAMETHRIN
Physical Properties
Molecular weight:350.5; Physical form:Pale yellow to yellow-brown clear liquid, with a faint characteristic odour. Density:1.06 (20 °C); Composition:The common name phenothrin refers to a mixture of (1RS)-cis-trans- isomers. d-Phenothrin contains 95% (1R)- isomers, 75% trans- isomer. Flash point:107 °C (Pensky-Martens closed test); Vapour pressure:1.9 ×10-2 mPa (21.4 °C); Henry constant:>6.75 ×10-1 Pa m3 mol-1 ( calc.); Partition coefficient(n-octanol and water):logP = 6.01 (20 °C); Solubility:In water <9.7µg/l (25 °C). In methanol >5.0, hexane >4.96 g/ml (25 °C).; Stability:Stable under normal storage conditions. Hydrolysed by alkalis.
Toxicology
Oral:Acute oral LD50 for rats >5000 mg/ kg. Percutaneous:Acute percutaneous LD50 for rats >2000 mg/ kg. Inhalation: LC50 (4 h) for rats >2100 mg/m3. ADI:0.03 mg/ kg.
Environmental Profile
Ecotoxicology: 
Bees:Toxic to bees.Birds:Acute oral LD50 for bobwhite quail >2500 mg/ kg.Daphnia: EC50 (48 h) 0.0043 mg/l.Fish: LC50 (96 h) for rainbow trout 2.7, bluegill sunfish 16µg/l. 

Environmental fate: 
Soil:Undergoes degradation by photo-oxidation. For details, see L. O. Ruzo et al., J. Agric. Food Chem., 1982, 30, 110.
Transport Information
Hazard Class:III(Slightly hazardous)

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