Dodemorph acetate

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Chemical Identification | General Product Information | Physical & Safety Data

Chemical Identification

Common Name

Dodemorph acetate

IUPAC

4-cyclododecyl-2,6-dimethylmorpholine acetate

CAS

4-cyclododecyl-2,6-dimethylmorpholine acetate (1:1)

CAS No.

31717-87-0

Molecular Formula

C₂₀H₃₉NO₃

Molecular Structure

General Product Information

Category

Fungicides > Morpholine fungicides

Activity

Fungicide

Physical & Safety Data

Physical Properties

Molecular weight:341.5; Physical form:Colourless solid; ( tech., viscous yellow liquid, acetic acid-like odor). Density:c. 0.93; Melting point:63-64 °C; cis- isomer 72 °C; Flash point:Forms flammable decomposition products at high temperature; Vapour pressure:2.5 mPa (20 °C); Henry constant:0.77 Pa m3 mol-1; Partition coefficient(n-octanol and water):logP = 2.52 ( pH 5), 4.23 ( pH 9); Solubility:In water 1.1 mg/kg (20 °C). In benzene, chloroform >1000, cyclohexane 846, ethyl acetate 205, ethanol 66, acetone 22 (all in g/ kg, 20 °C). Stability:Stable in unopened containers for >1 y. Stable at 50 °C for 2 y. Stable in neutral, moderate alkaline or acidic media. Solubility (at 20°): in ether 74.3 g/100g; chloroform 100 g/100g; cyclohexane 84.6g/100g; benzene 100g/100g.

Toxicology

Oral:Acute oral LD₅₀ for male rats 3944 mg/kg, female rats 2465 mg/kg. Percutaneous:Acute percutaneous LD₅₀ for rats >4000 mg/kg (for 42.6% EC formulation). Skin irritant and severe eye irritant (rabbits). Inhalation: LC₅₀ (4 h) for rats 5 mg/l air (for EC formulation). Phytotoxicity:Cinerarias, begonias, and some varieties of rose may be injured.

Environmental Profile

Ecotoxicology:
Bees:Non-toxic to bees.Daphnia: LC₅₀ (48 h) 3.34 mg/l.Fish: LC₅₀ (96 h) for guppies c. 40 mg/l. LC₅₀ ca. 12 mg/l (trout). Bird: Oral LD₅₀ ca. 3000 mg/kg b.w. (quail).
Environmental fate:
Soil: DT₅₀ 73 d. K_oc 4200-48 000, indicating high adsorption and therefore no risk of leaching.
WATER SOLUBILITY: 1.1 mg/kg at 20°C.
DEGRADATION/METABOLISM: Slow degradation.

Transport Information

Hazard Class:III (Slightly hazardous)

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Dodemorph acetate

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