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Chemical Identification
Common Name
Etofenprox
中文通用名
醚菊酯
IUPAC
2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether
CAS
1-[[2-(4-ethoxyphenyl)-2-methylpropoxy]methyl]-3-phenoxybenzene
CAS No.
80844-07-1
Molecular Formula
C25H28O3
Molecular Structure
Category
Activity
Mode of action Insecticide with contact and stomach action. Uses Control of rice water weevils, skippers, leaf beetles, leafhoppers, planthoppers, and bugs on paddy rice; and aphids, moths, butterflies, whitefly, leaf miners, leaf rollers, leafhoppers, thrips, borers, etc. on pome fruit, stone fruit, citrus fruit, tea, soya beans, sugar beet, brassicas, cucumbers, aubergines, and other crops. Also used to control public health pests, and on livestock.
CropUse
pome fruit, stone fruit, citrus fruit, tea, soya beans, sugar beet, brassicas, cucumbers, aubergines, and other crops.
Pest Spectrum
Control of rice water weevils, skippers, leaf beetles, leafhoppers, planthoppers, and bugs on paddy rice; and aphids, moths, butterflies, whitefly, leaf miners, leaf rollers, leafhoppers, thrips, borers, etc
Formulation
CS = Capsule suspension
DP = Dustable powder
GR = Granule
UL = Ultra-low volume liquid
WP = Wettable powder
Physical Properties
Molecular weight:376.5; Physical form:White crystals. Density:1.157 (23 °C, solid); 1.067 (40.1 °C, liquid); Melting point:36.4-38.0 °C; Vapour pressure:32 mPa (100 °C); Partition coefficient(n-octanol and water):logP = 7.05 (25 °C); Solubility:In water <1 μg/l (25 °C). In chloroform 9, acetone 7.8, ethyl acetate 6, xylene 4.8, methanol 0.066 (all in kg/l, 25 °C).; Stability:Stable in acidic and alkaline media at 80 °C for >90 days, and to light.
Toxicology
Oral:Acute oral LD50 for male and female rats >42 880, male mice >107 200, dogs >5000 mg/ kg. Percutaneous:Acute percutaneous LD50 for rats and male and female mice >2140 mg/ kg; non-irritating to skin and eyes (rabbits). Inhalation: LC50 (4 h) for rats 5900 mg/m3. ADI:0.044 mg/ kg b.w.
Environmental Profile
Ecotoxicology: 
Birds:Acute oral LD50 for mallard ducks >2000 mg/ kg.Daphnia: LC50 (3 h) >40 mg/l.Fish: TLm (48 h) for carp 5.0 ppm.Worms: LC50 for earthworms (7 d) 43.1 ppm, (14 d) 24.6 ppm. 

Environmental fate: 
Animals:In rats, parent compound, 2-(4-hydroxyphenyl)-2-methylpropyl 3-(phenoxybenzyl) ether, and 2-(4-ethoxyphenyl)-2-methylpropyl 3-(4-hydroxybenzyl) ether are found.Soil: DT50 in soil c. 6 d.Plant:In rice, the main metabolite is 2-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzoate.
Transport Information
Signal Word:CAUTION; Hazard Class:III(Slightly hazardous)

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Country:  China

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