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Imidazolinone herbicides
hexaconazole
Chemical Identification
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General Product Information
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Physical & Safety Data
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Shared Information
Chemical Identification
Edit
Common Name
hexaconazole
中文通用名
己唑醇
IUPAC
(
RS
)-2-(2,4-dichlorophenyl)-1-(1
H
-1,2,4-triazol-1-yl)hexan-2-ol
CAS
α-butyl-α-(2,4-dichlorophenyl)-1
H
-1,2,4-triazole-1-ethanol
CAS No.
79983-71-4
Molecular Formula
C
14
H
17
Cl
2
N
3
O
Molecular Structure
General Product Information
Edit
Category
Fungicides > Triazole fungicides
Activity
Fungicide
Premix
chlorothalonil+hexaconazole
Oil miscible liquid, soluble grain, suspension concentrate.
Premix Parters: dicofol; propargite.
Physical & Safety Data
Edit
Physical Properties
Molecular weight:314.2g/mol; Physical form:White, crystalline solid. Density:1.29 g/cm3 (25℃); Composition:Tech. is >85% pure. Melting point:110-112℃; Vapour pressure:0.018 mPa (20℃); Henry constant:3.33 × 10-4 Pa m3 mol-1 ( calc.); Partition coefficient(n-octanol and water):logP = 3.9 (20℃); Solubility:In water 0.017 g/l (20℃). In dichloromethane 336, methanol 246, acetone 164, ethyl acetate 120, toluene 59, hexane 0.8 (all in g/l, 20℃).; Stability:Stable for at least 6 years at ambient temperatures. Stable to hydrolysis and photolysis in water. Formulations stable in sales containers for 6 months at 50℃, and 2 years at ambient temperature.
Toxicology
Oral:Acute oral LD
50
for male rats 2189, female rats 6071 mg/ kg. Percutaneous:Acute percutaneous LD
50
for rats >2000 mg/kg. Mild irritant to eyes; non-irritating to skin (rabbits). Moderate skin sensitiser (guinea pigs). Inhalation: LC
50
(4 h) for rats >5.9 mg/l. Phytotoxicity:Non-phytotoxic when used as directed. Some injury noted on McIntosh apples. ADI:( JMPR) Conditional ADI withdrawn [1978].
Environmental Profile
Ecotoxicology:
Bees:Acute oral and contact LD
50
for honeybees >0.1 mg/bee.Birds:Acute oral LD
50
for mallard ducks >4000 mg/ kg.Daphnia: LC
50
(48 h) 2.9 mg/l.Fish: LC
50
(96 h) for rainbow trout 3.4, mirror carp 5.94, sheepshead minnow 5.4 mg/l.Worms: LC
50
(14 d) 414 mg/ kg.
Environmental fate:
Animals:Readily excreted by mammals, with no significant retention in organs or tissues.Soil:Rapidly degraded in soils in laboratory tests.Plant:For details of the metabolism of hexaconazole in cereals, see M. W. Skidmore
et al., Br. Crop Prot. Conf. - Pests Dis.
, 1990,
3
, 1035-1040.
Transport Information
Signal Word:CAUTION; Hazard Class:III(Slightly hazardous)
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ICAMA Report
Hexaconazole TC - ICAMA Registration Report
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Product
hexaconazole
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