Chemical Identification
Common Name
Cartap hydrochloride
IUPAC
S,S′-(2-dimethylaminotrimethylene) bis(thiocarbamate) hydrochloride
CAS
S,S′-[2-(dimethylamino)-1,3-propanediyl] dicarbamothioate monohydrochloride
CAS No.
15263-52-2
Molecular Formula
C7H16ClN3O2S2
Molecular Structure
Category
Activity
Insecticide
Premix
Dust, granule, water-soluble powder. Premix Parters: desmedipham phenmedipham; ethofumesate; lenacil; metolachlor; phenmedipham quinmerac; quinmerac; triallate;
Physical Properties
Molecular weight:273.8; Physical form:Colourless crystalline, slightly hygroscopic solid with slight odour. Melting point:179-181 °C (decomp.); Vapour pressure:Negligible; Solubility:In water c. 200 g/l (25 °C). Very slightly soluble in methanol and ethanol. Insoluble in acetone, diethyl ether, ethyl acetate, chloroform, benzene, and hexane.; Stability:Stable in acidic conditions, but hydrolysed in neutral or alkaline media. Stable in acidic conditions. Slightly soluble in ethanol, methanol. Insoluble in acetone, benzene, chloroform, diethyl ether, ethyl acetate, and n-hexane.
Toxicology
Oral:Acute oral LD50 for male rats 345 mg/kg, female rats 325 mg/kg, male mice 150, female mice 154 mg/kg. Percutaneous:Acute percutaneous LD50 for mice >1000 mg/kg; no irritation to skin or eyes in rabbits. Inhalation:LC50 (6 h) for rats >0.54 mg/l. Phytotoxicity:May be phytotoxic to cotton, tobacco, and apples, under certain soil and climatic conditions. ADI:(JMPR) ADI withdrawn [1995].
Environmental Profile
Ecotoxicology: Bees:Moderately toxic to honeybees.Fish:LC50 for carp 1.6 mg/l (24 h) and 1.0 mg/l (48 h).Other aquatic spp.:LC50 (24 h) for Moina macrocopa 12.5-25 mg/l. Environmental fate: Animals:In rats, the carbonyl carbon is hydrolysed, and the sulfur oxidised, with N-demethylation of thiomethyl derivatives. No accumulation occurs in tissues. Rapidly excreted in the urine.Soil:DT50 in soil c. 3 d. WATER SOLUBILITY: Hydrolyzed in neutral or alkaline solution
Transport Information
Signal Word:WARNING; Hazard Class:II (Moderately hazardous)

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