Fluoroglycofen-ethyl

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Chemical Identification | General Product Information | Physical & Safety Data

Chemical Identification

Common Name

中文通用名

乙羧氟草醚

IUPAC

ethyl O-[5-(2-chloro-α,α,α-trifluoro-p-tolyloxy)-2-nitrobenzoyl]glycolate

CAS

2-ethoxy-2-oxoethyl 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate

CAS No.

77501-90-7

Molecular Formula

C₁₈H₁₃ClF₃NO₇

Molecular Structure

General Product Information

Category

Herbicides > Diphenyl ether herbicides

Activity

Herbicide

Premix

Tribenuron-methyl+fluoroglycofen-ethyl
Glyphosate ammonium+MCPA+Fluoroglycofen-ethyl
Fluoroglycofen-ethyl+Quizalofop-p-ethyl+Glyphosate
Fluoroglycofen-ethyl+Haloxyfop-P-methyl
Fluoroglycofen-ethyl+Glufosinate-ammonium
Bensulfuron-methyl+Fluoroglycofen-ethyl+Clodinafop-propargyl
Emulsifiable concentrate, wettable powder.
Premix Parters: mancozeb;

Physical & Safety Data

Physical Properties

Molecular weight:447.8; Physical form:Dark amber solid. Density:1.01 (25 °C); Melting point:65 °C; Partition coefficient(n-octanol and water):logP = 3.65; Solubility:In water 0.6 mg/l (25 °C). Readily soluble in most organic solvents (except hexane).; Stability:In aqueous solution, 0.25 mg/l, at 22 °C, DT50 c. 231 d ( pH 5), 15 d ( pH 7), 0.15 d ( pH 9)

Toxicology

Oral:Acute oral LD₅₀ for rats 1500 mg/ kg. Percutaneous:Acute percutaneous LD₅₀ for rabbits >5000 mg/ kg; slight irritant to their skin and eyes. Inhalation: LC₅₀ (4 h) for rats >7.5 mg EC formulation/l.

Environmental Profile

Ecotoxicology:
Bees: LD₅₀ (contact) >100 μg/bee.Birds:Acute oral LD₅₀ for bobwhite quail >3160 mg/kg. Dietary LC₅₀ (8 d) for mallard ducks and bobwhite quail >5000 mg a.i./ kg.Daphnia: LC₅₀ (48 h) 30 mg/l.Fish: LC₅₀ (96 h) for bluegill sunfish 1.6, trout 23 mg/l.

Environmental fate:
Animals:Hydrolysis of the ester and reduction of the nitro group.Soil:In soil and water, fluoroglycofen-ethyl is very rapidly hydrolysed to the corresponding acid.
SOIL PARTICLE ADSORPTION: Low potential to leach DEGRADATION/METABOLISM: Soil photolysis half-life 14 days; aqueous photolysis half-life 3-6 hr

Transport Information

Signal Word:CAUTION; Hazard Class:III(Slightly hazardous)