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Chemical Identification
Common Name
Dimethylvinphos
中文通用名
甲基毒虫畏
IUPAC
(Z)-2-chloro-1-(2,4-dichlorophenyl)vinyl dimethyl phosphate
CAS
(1Z)-2-chloro-1-(2,4-dichlorophenyl)ethenyl dimethyl phosphate
CAS No.
2274-67-1
Molecular Formula
C10H10Cl3O4P
Molecular Structure
Physical Properties
Molecular weight:331.5. Physical form:Pale white, crystalline solid. Density:1.26 (25 °C); Composition:Comprises >95.0% (Z)- isomer, <2.0% (E)- isomer. The diethyl ester analogue (mixture of (E)- and (Z)- isomers) is chlorfenvinphos ( q.v.). Melting point:69-70 °C; Vapour pressure:1.3 mPa (25 °C); Partition coefficient(n-octanol and water):logP = 3.12 (25 °C); Solubility:In water 130 ppm (20 °C). In xylene 300-350, acetone 350-400, cyclohexanone 450-500 g/l (20 °C). Stability:Hydrolysis DT50 40 d ( pH 7.0, 25 °C). Unstable in sunlight.
Toxicology
Oral:Acute oral LD50 for rats 155-210, mice 200-220 mg/kg. Percutaneous:Acute percutaneous LD50 for rats 1360-2300 mg/kg. Inhalation: LC50 (4 h) for male rats 970-1186, female rats >4900 mg/m3. Phytotoxicity:Non-phytotoxic to most crops at recommended doses. Spotting seen on peach leaves.
Environmental Profile
Ecotoxicology: 
Daphnia: LC50 (24 h) 0.002 ppm.Fish: LC50 (24 h) for carp 2.3 ppm.
Transport Information
Hazard Class:O (Obsolete as pesticide, not classified)

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