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Chemical Identification
Common Name
Hexazinone
中文通用名
环嗪酮
IUPAC
3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione
CAS
3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione
CAS No.
51235-04-2
Molecular Formula
C12H20N4O2
Molecular Structure
Category
Activity
Herbicide
Premix
Sulfometuron-methyl+hexazinone
Hexazinone+Diuron
Granule, water-soluble granule, water-soluble liquid, and undiluted liquid applied with exact delivery handgun.
Premix Parters: copper oxychloride;
Physical Properties
Molecular weight:252.3g/mol; Physical form:Colourless, odourless crystals. Density:1.25; Melting point:115-117℃; Vapour pressure:0.03 mPa (extrapolated) (25℃); 8.5 mPa (86℃); Partition coefficient(n-octanol and water):logP = 1.2 ( pH 7); Solubility:In water 33 g/ kg (25 ℃). In chloroform 3880, methanol 2650, benzene 940, dimethylformamide 836, acetone 792, toluene 386, hexane 3 (all in g/ kg, 25℃).; Stability:Stable in aqueous media between pH 5 and pH 9 and below 37 ℃. Decomposed by strong acids and strong alkalis. Stable to light.
Toxicology
Oral:Acute oral LD50 for rats 1690, guinea pigs 860 mg/ kg. Percutaneous:Acute percutaneous LD50 for rabbits >5278 mg/kg. Reversible irritant to eyes (rabbits); non-irritating to skin (guinea pigs). Inhalation: LC50 (1 h) for rats >7.48 mg/l. Phytotoxicity:Should not be used for weed control in larch (Larix spp.) or in areas planted with deciduous species. ADI:0.02 mg/ kg b.w.
Environmental Profile
Ecotoxicology:
Bees:Not toxic to bees; LD50 >60 μg/bee. Birds:Acute oral LD50 for bobwhite quail 2258 mg/kg. Dietary LC50 (8 d) for bobwhite quail and mallard ducklings >10 000 mg/ kg diet.Daphnia: LC50 (48 h) 442 mg/l.Fish: LC50 (96 h) for rainbow trout 320-420, fathead minnow 274, bluegill sunfish 370-420 mg/l.

Environmental fate:
Animals:Major urinary metabolites in rats are 3-(4-hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H)-dione, 3-cyclohexyl-6-(methylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H)-dione, and 3-(4-hydroxycyclohexSoil:Microbial degradation occurs in soil and natural waters. The triazine ring is broken, with the liberation of CO2. DT50 in soil c. 1-6 mo, depending on climate and soil type.
Transport Information
Signal Word:DANGER; Hazard Class:Ib(Highly hazardous)

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